Product ID:REFRIGERANT 113
MSDS Date:11/21/1994
FSC:6850
NIIN:00-033-8851
MSDS Number: BPBRK

Emergency Phone: 201-796-7100/800-424-9300(CHEMTREC)

Info Phone: 201-796-7100 OR 201-796-7523

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000PPM/1250STEL9495

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- EYES/SKIN:CAN CAUSE IRRITATION.
INHALE:AT LEVEL OF 500 PPM, IMMEDIATELY DANGEROUS TO LIFE/HEALTH.
OVEREXPOSURE MAY CAUSE ASPHYXIATION, SE NSITIZATION OF HEART,
SUDDEN DEATH. ORAL:MAY CAUSE CNS DEPRESSION & ARRHYTHMIA. CHRONIC-
DERMATITIS, IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, ABDOMINAL PAIN,
HEADACHE, DROWSINESS, DIZZINESS, TEARING, BLURRED VISION, DRYNESS
OF SKIN, DERMATITIS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED CNS OR RESPIRATORY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.

First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES, HOLDING EYELIDS OPEN. CONSULT A PHYSICIAN. SKIN:REMOVE
CONTAMINAT ED CLOTHING. WASH SKIN WITH PLENTY OF SOAP AND WATER.
ORAL:DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY. IF
VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:1256F
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, REGULAR FOAM/DRY
CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING & NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. DON'T SCATTER FIRE WITH
HIGH-ORESSURE WATER STREAM. 93 EMERGENCY RESPONSE GUIDE 31
Unusual Fire/Explosion Hazard:NEGLIGIBLE. CONCENTRATED VAPORS MAY BE
IGNITED BY HIGH INTENSITY IGNITION SOURCE. MAY FORM HIGHLY TOXIC
AND IRRITATING GASES.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA.
STOP LEAK IF POSSIBLE. ABSORB SPILLS WITH INERT MATERIAL SUCH AS
SAND/VERMICULITE OR USE PUMP. PLACE IN SUITABLE CONTAINERS FOR
DISPOSAL. DO NOT FLUSH TO SEW ER OR WATERWAYS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN COOL, DRY, VENTILATED PLACE
AWAY FROM INCOMPATIBLES. KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:VAPORS HEAVIER THAN AIR AND WILL COLLECT IN LOW
AREAS. WEAR RESPIRATOR BEFORE ENETERING LOW AREAS. DO NOT CUT OR
WELD ON EMPTY OR FULL CONTAINERS. WASH THOROUGHLY AFTER HANDLING
AND BEFORE EATING, DRI NKING. KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:WEAR NIOSH-APPROVED FULL FACE ORGANIC VAPOR
RESPIRATOR. FOR HIGH VAPOR CONCENTRATIONS, USE SELF-CONTAINED
BREATHING APPARATUS OR AIR LINE RESPIRATOR WITH FULL FACEPIECE.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:VITON, POLYVINYL ALCOHOL (PVA)
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health

HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:114F,46C
Vapor Pres:284 @ 68F
Vapor Density:APROX. 6
Spec Gravity:1.6
Evaporation Rate & Reference:0.45 (ACETONE=1)
Solubility in Water:0.28%
Appearance and Odor:COLORLESS LIQUID - AMMONIA LIKE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI METALS, POWDER OF ALUMINUM, BARIUM, LITHIUM AND TITINIUM,
BERYLLIUM, MAGNESIUM, PLASTIC, RUBBER, ZINC
Stability Condition to Avoid:OPEN FLAME, ELECTRIC ARCS, HOT SURFACES
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CARBON MONOXIDE,
CARBON DIOXIDE, PHOSGENE, CHLORINE, HYDROGEN FLUORIDE MAY BE
FORMED.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. AVOID CONTAMINATION OF GROUND AND SURFACE
WATER.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.